余氯分析儀構(gòu)成和工作原理-深圳市慧聰源環(huán)?？萍加邢薰?/title> <link rel="stylesheet" type="text/css" href="/skins/270528/css/style.css"> <script src="/skins/270528/js/jquery-3.6.0.min.js"></script> <link rel="shortcut icon" href="/skins/270528/favicon.ico">  <script type="text/javascript"> document.addEventListener("touchstart", function () { }, true); </script>  <script language="javascript" type="text/javascript"> var nav= '5'; </script>  <script type="application/ld+json"> { "@context": "https://ziyuan.baidu.com/contexts/cambrian.jsonld", "@id": "http:///szhcy-Article-2057534/", "title": "余氯分析儀構(gòu)成和工作原理", "pubDate": "2019-12-07T09:33:35", "upDate": "2019-12-07T09:33:35" }</script> <script language="javaScript" src="/js/JSChat.js"></script><script language="javaScript">function ChatBoxClickGXH() { DoChatBoxClickGXH('https://chat.chem17.com',262687) }</script><script> (function(){ var bp = document.createElement('script'); var curProtocol = window.location.protocol.split(':')[0]; if (curProtocol 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<div id="qprrcczb" class="ly_NyNewsdetail"> <h1 class="NyNewsdetail_title">余氯分析儀構(gòu)成和工作原理</h1> <div id="qprrcczb" class="NyNewsdetail_tips">更新時間：2019-12-07 點擊次數(shù)：3263</div> <div id="qprrcczb" class="NyNewsdetail_con"> <p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 目前，</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">在線余氯分析儀</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">有電化學(xué)式和分光光度計式兩類，本節(jié)僅介紹電化學(xué)式。電化學(xué)式</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">余氯分析儀</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">大多采用隔膜電解池式傳感器，這種</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">余氯傳感器</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">由金制的測量電極和銀制的反電極組成，</span></span><span style="font-size:10.5pt"><span style="font-family:宋體">電極</span></span><span style="font-size:10.5000pt"><span style="font-family:宋體">浸入含有氯化物離子的電解質(zhì)溶液中、電極和電解液由隔膜與被測介質(zhì)隔離，然而允許氣體擴(kuò)散穿過。隔膜的作用是防止電解液流失及被測液體中的污染物滲透進(jìn)來引起中毒。</span></span></p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 測量時，電極之間加一個固定的極化電壓，電極和電解液便構(gòu)成了一個電解池。隔膜傳感器具有選擇性，能擴(kuò)散通過隔膜的化合物是游離氯，能在電極上起反應(yīng)的是次氯酸 (HCI0) ,即有效游離氯。傳感器上發(fā)生下列電極反應(yīng): </span></span></p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 測量電極(金陰極): HOCI+2e</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:arial">→</span></span><span style="font-size:10.5000pt"><span style="font-family:宋體">OH</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體"> +CI</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup> </p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 反電極(銀陽極): 2Ag+2CI</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:arial">→</span></span><span style="font-size:10.5000pt"><span style="font-family:宋體">2Agcl十2e</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup> </p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 連續(xù)不斷的電荷遷移產(chǎn)生電流，電流強度與次氯酸濃度成正比。 </span></span></p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> E+H公司CCS140型</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">余氯傳感器探頭</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">的結(jié)構(gòu)見圖14-18。</span></span></p><p> <img src="http://img71.chem17.com/9/20191207/637113076716760665976.png" style="height:306px; width:293px" /> </p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 游離氯是HOCl和OCI</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體">兩者之和，上面的電極反應(yīng)只能測得HOCI(次氯酸)，OCI</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體"> (次氯酸根)卻無法與電極發(fā)生反應(yīng)而檢測不到。根據(jù)式(14-8) HOC1=H</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">+</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體">+OCl</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體">，所以只需測出H</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">+</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體">的濃度就可以推算出OCl</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">-</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體">的濃度，H</span></span><sup><span style="font-size:10.5000pt"><span style="font-family:宋體">+</span></span></sup><span style="font-size:10.5000pt"><span style="font-family:宋體">的濃度可以通過</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">pH計</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">來測出，所以測量游離氯的時候需要pH補償。 </span></span></p><p><span style="font-size:10.5000pt"><span style="font-family:宋體"> 考慮到</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">余氯分析儀</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">測量時需要一定的樣品流速，測量結(jié)果還需要進(jìn)行溫度補償和pH值校正，一般是將</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">余氯傳感器</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">、鉑電阻測溫元件、</span></span><strong><span style="font-size:10.5pt"><span style="font-family:宋體">pH電極</span></span></strong><span style="font-size:10.5000pt"><span style="font-family:宋體">和浮子流量計組裝在一起，做成一個測量組件。 </span></span></p> </div> <div id="qprrcczb" class="ly_PrevNext"> <ul> <li>上一篇：<a href="/szhcy-Article-2057878/">計量泵的日常保護(hù)措施有哪些</a></li> <li>下一篇：<a href="/szhcy-Article-2056210/">氨氮水質(zhì)自動分析儀檢驗方法</a></li> </ul> </div> </div>   <div id="qprrcczb" class="foot_box"> <div id="qprrcczb" class="foot_t"> <div id="qprrcczb" class="w1200"> <a href="/">網(wǎng)站首頁</a>　|　<a href="/aboutus.html">關(guān)于我們</a>　|　<a href="/products.html">產(chǎn)品中心</a>　|　<a href="/news.html">新聞動態(tài)</a>　|　<a href="/article.html">技術(shù)文章</a>　|　<a href="/honor.html">榮譽資質(zhì)</a>　|　<a href="/order.html" target="_blank">在線留言</a>　|　<a href="/contact.html">聯(lián)系我們</a> <span><a href="javascript:;" class="toTop"></a></span> </div> </div> <div id="qprrcczb" 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